The first hydrogen bonded anionic phosphates exhibiting sulfur donor coordination

被引：16

作者：

Chandrasekaran, A ^{[1
]}

Sood, P ^{[1
]}

Day, RO ^{[1
]}

Holmes, RR ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 18期

关键词：

D O I：

10.1021/ic990486o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have synthesized and structurally characterized the first anionic phosphates undergoing sulfur donor action in the presence of hydrogen bonding. As a consequence, these phosphates increase their coordination geometry toward a trigonal bipyramid. It is suggested that such action may occur at active sites of phosphoryl transfer enzyme containing anionic phosphate substrates.

引用

页码：3952 / +

页数：3

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