Synthesis, properties and structural characterization of an intermolecular photosensitive complex:: (HGly-Gly)3PMo12O40•4H2O

被引：71

作者：

Han, ZB

Wang, EB ^{[1
]}

Luan, GY

Li, YG

Zhang, H

Duan, YB

Hu, CW

Hu, NH

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

[2] NE Gen Pharmaceut Factory, Shenyang 110026, Peoples R China

[3] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 04期

关键词：

D O I：

10.1039/b107225k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first heteropoly acid-dipeptide complex, (HGly-Gly)(3)PMo12O40.4H(2)O, was synthesized and characterized by elemental analysis, IR, UV, H-1 NMR and single crystal X-ray diffraction. The X-ray crystallographic study showed that the crystal structure was constructed from N-H...O and O-H...O hydrogen bonds among the (HGly-Gly)(+), H2O and PMo12O403- units. This structure represents a model interaction between polyoxometalates and proteins. The complex has photosensitivity under irradiation by sunlight. The fluorescent activity of this compound is also reported.

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页码：1169 / 1173

页数：5

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