Electroreductive synthesis and optical characterization of silicon nanoparticles

被引:17
作者
Aihara, S
Ishii, R
Fukuhara, M
Kamata, N
Terunuma, D
Hirano, Y
Saito, N
Aramata, M
Kashimura, S
机构
[1] NHK Japan Broadcasting Corp, Adv Imaging Dev Res Div, Setagaya Ku, Tokyo 1578510, Japan
[2] Saitama Univ, Dept Funct Mat Sci, Saitama, Saitama 3388570, Japan
[3] Shin Etsu Chem Co Ltd, Gunma 3790195, Japan
[4] Kinki Univ, Fac Sci & Technol, Osaka 5778502, Japan
关键词
D O I
10.1016/S0022-3093(01)00923-1
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Electroreduction of tetrachlorosilane was carried out to fabricate silicon (Si) nanoparticles for the first time. Typical size of the obtained particles is 3 nm. The transmission electron microscopy (TEM) and the electron diffraction pattern of the particles revealed that each particle consists only of an amorphous phase. Optical absorption at 5.1 eV and visible photoluminescence (PL) around 2.74 eV were observed for the particles at room temperature. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:135 / 138
页数:4
相关论文
共 16 条
[1]   Determination of oxygen in organosilicon polymers and organic materials by inert-gas fusion with a platinum-carbon converter [J].
Aramata, M ;
Igarashi, T ;
Okayama, J ;
Ikeda, M .
ANALYTICAL SCIENCES, 1998, 14 (03) :541-546
[2]   COMPETITIVE ELECTROCHEMICAL SYNTHESIS OF POLYDIMETHYLSILANE WITHOUT SOLVENT [J].
BORDEAU, M ;
BIRAN, C ;
LEGERLAMBERT, MP ;
DUNOGUES, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (20) :1476-1477
[3]   Optical properties of passivated Si nanocrystals and SiOx nanostructures [J].
Dinh, LN ;
Chase, LL ;
Balooch, M ;
Siekhaus, WJ ;
Wooten, F .
PHYSICAL REVIEW B, 1996, 54 (07) :5029-5037
[4]   PHOTOLUMINESCENCE OF OXIDIZED SILICON NANOCLUSTERS DEPOSITED ON THE BASAL-PLANE OF GRAPHITE [J].
DINH, LN ;
CHASE, LL ;
BALOOCH, M ;
TERMINELLO, LJ ;
WOOTEN, F .
APPLIED PHYSICS LETTERS, 1994, 65 (24) :3111-3113
[5]   OPTICAL-PROPERTIES OF SILICON NETWORK POLYMERS [J].
FURUKAWA, K ;
FUJINO, M ;
MATSUMOTO, N .
MACROMOLECULES, 1990, 23 (14) :3423-3426
[6]   Fabrication of nanometer sized Si dot multilayers and their photoluminescence properties [J].
Hirano, Y ;
Sato, F ;
Saito, N ;
Abe, M ;
Miyazaki, S ;
Hirose, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 266 :1004-1008
[7]   Decay dynamics of visible luminescence in amorphous silicon nanoparticles [J].
Kanemitsu, Y ;
Fukunishi, Y ;
Kushida, T .
APPLIED PHYSICS LETTERS, 2000, 77 (02) :211-213
[8]   VISIBLE PHOTOLUMINESCENCE FROM OXIDIZED SI NANOMETER-SIZED SPHERES - EXCITON CONFINEMENT ON A SPHERICAL-SHELL [J].
KANEMITSU, Y ;
OGAWA, T ;
SHIRAISHI, K ;
TAKEDA, K .
PHYSICAL REVIEW B, 1993, 48 (07) :4883-4886
[9]   Electroreductive synthesis of polysilanes, polygermanes, and related polymers with magnesium electrodes [J].
Kashimura, S ;
Ishifune, M ;
Yamashita, N ;
Bu, HB ;
Takebayashi, M ;
Kitajima, S ;
Yoshiwara, D ;
Kataoka, Y ;
Nishida, R ;
Kawasaki, S ;
Murase, H ;
Shono, T .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (18) :6615-6621
[10]   POLYSILANE HIGH POLYMERS [J].
MILLER, RD ;
MICHL, J .
CHEMICAL REVIEWS, 1989, 89 (06) :1359-1410