Electrospray mass spectrometric detection of unstable rhenium complexes as reaction intermediates of photochemical CO2-fixation

被引：15

作者：

Hori, H ^{[1
]}

Ishitani, O ^{[1
]}

Koike, K ^{[1
]}

Takeuchi, K ^{[1
]}

Ibusuki, T ^{[1
]}

机构：

[1] SAITAMA UNIV,GRAD SCH SCI & TECHNOL,URAWA,SAITAMA 338,JAPAN

来源：

ANALYTICAL SCIENCES | 1996年 / 12卷 / 04期

关键词：

electrospray mass spectrometry; reaction intermediate; rhenium complex; triethanolamine complex;

D O I：

10.2116/analsci.12.587

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Reaction intermediates of CO2-photofixation using [Re(bpy)(CO)(3)PPh(3)](+)(bpy=2,2'-bipyridine) have been studied by electrospray mass spectrometry. A triethanolamine (TEOA) complex, [Re(bpy)(CO)(3)(TEOA)](+), was detected for the first time as a key intermediate. Electrospray mass spectrometry was found quite useful for detecting and identifying unstable photoreaction intermediates of rhenium complexes.

引用

页码：587 / 590

页数：4

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