Nanocrystal Plasma Polymerization: From Colloidal Nanocrystals to Inorganic Architectures

Nanocrystal superstructures are increasingly becoming a subject of intense study. Such materials could constitute a new class of nanocomposites of designed structure, of homogeneous composition, and with unique properties. New phenomena are observed in these materials because of the interaction at such diminutive length scales. A common problem in the development of devices relying on colloidal nanocrystal assemblies is that the individual nanocrystal building blocks require organic molecules to control their size. These ligands are responsible for the colloidal stability of the individual nanocrystal building blocks and are thus necessary for their solution processibility. Because of the ligands incompatibility with many solid state applications, it is important to develop post-processing techniques that mildly remove them from these nanocomposites, while maintaining the size-dependent properties of the building blocks. This Account highlights a new strategy, nanocrystal plasma polymerization (NPP), for processing colloidal nanocrystal assemblies. This technique exposes the nanocomposite to a mild air plasma and allows for the removal of the nanocrystals' capping ligands while preserving their size-dependent and material properties. As a result, the process yields a nearly all-inorganic flexible solid-state material with unprecedented characteristics. We describe early experiments, in which NPP was used to create arbitrarily complex ID, 2D, and 3D inorganic freestanding architectures entirely composed of nanocrystals, as well as future directions and challenges. We expect this platform will be useful for the design of new materials and will be a valuable new addition to the nanoscientist's toolbox.