The Use of Calixarenes in Metal-Based Catalysis

被引：405

作者：

Homden, Damien M. ^{[1
]}

Redshaw, Carl ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci & Pharm, Energy Mat Lab, Norwich NR4 7TJ, Norfolk, England

来源：

CHEMICAL REVIEWS | 2008年 / 108卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/cr8002196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was conducted to demonstrate the use of calixarenes in metal-based catalysis. The study focused on rare earth metal-containing species,including neodymium to demonstrate the use of calixarenes in metal-based catalysis. It was found that the ability to make calixarenes water-soluble allowed them to be used as catalysts in aqueous media, demonstrating that calixarene-based systems were employed as homo- or heterogeneous catalysts. It was demonstrated that the availability of chiral calixarenes offered significant advantages for calixarene-based catalysis of metals. It was also demonstrated that the characteristics and availability of calixarenes made them potentially environmentally friendly for catalytic applications in academic research activities and industrial processes.

引用

页码：5086 / 5130

页数：45

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