Conical cavitands as second coordination spheres and protecting environments. towards metal-centred, intra-cavity reactions

被引：22

作者：

Armspach, D. ^{[1
]}

Bagatin, I. ^{[1
]}

Engeldinger, E. ^{[1
]}

Jeunesse, C. ^{[1
]}

Harrowfield, J. ^{[1
]}

Lejeune, M. ^{[1
]}

Matt, D. ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7513, Lab Chim Inorgan Mol, F-67008 Strasbourg, France

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2004年 / 1卷 / 01期

关键词：

metallocavitands; calixarenes; cyclodextrins; supramolecular catalysis;

D O I：

10.1007/BF03245765

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metallocavitands are coordination compounds based on rigidified molecular cavities which possess at least one entry. Those in which the metal centre is rigidly held above the entrance are particularly promising for the study of host-guest interactions between metal-bonded substrates and the internal part of a cavity. Such systems also open the way to highly selective intra-cavity reactions. The present review focusses on conical cavities derived from calixarenes and cyclodextrins and examines their possible use as second coordination sphere ligands.

引用

页码：10 / 19

页数：10

共 35 条

[1]

Armspach D, 2003, EUR J INORG CHEM, P805

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