Hexahomotrioxacalix[3]arene:: a scaffold for a C3-symmetric phosphine ligand that traps a hydrido-rhodium fragment inside a molecular funnel

被引：29

作者：

Dieleman, CB

Matt, D

Neda, I

Schmutzler, R

Harriman, A

Yaftian, R

机构：

[1] Grp Chim Inorgan Mol, CNRS, UMR 7513, F-67008 Strasbourg, France

[2] Tech Univ Braunschweig, Inst Anorgan Chem & Analyt Chem, D-38023 Braunschweig, Germany

[3] Ecole Europeenne Chim Polymeres & Mat, F-67008 Strasbourg, France

[4] Univ Zandjan, Dept Chem, Zandjan 45195, Iran

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a905677g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stereoselectivity around an H-Rh-CO fragment has been realized by reaction of the hexahomotrioxacalix[3]arene-derived triphosphine 4 with [Rh(acac)(CO)(2)]; the resultant trigonal bipyramidal complex has the Rh-H bond directed inside the cavity.

引用

页码：1911 / 1912

页数：2

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