A methodology for quantifying sodalite and cancrinite phase mixtures and the kinetics of the sodalite to cancrinite phase transformation

被引：79

作者：

Barnes, MC ^{[1
]}

Addai-Mensah, J ^{[1
]}

Gerson, AR ^{[1
]}

机构：

[1] Univ S Australia, Ian Wark Res Inst, Adelaide, SA 5095, Australia

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 1999年 / 31卷 / 03期

基金：

澳大利亚研究理事会;

关键词：

sodalite; scale; cancrinite; phase transformation; kinetics;

D O I：

10.1016/S1387-1811(99)00080-3

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A simple methodology for determining the cancrinite proportion of a sodalite and cancrinite phase mixture was developed using powder X-ray diffraction. Using this :methodology to quantify phase mixtures, the kinetics of the sodalite to cancrinite phase transformation were determined. The transformation reaction leading to cancrinite formation was found to be first order with respect to the relative concentration of sodalite. Over the temperature range 160-240 degrees C, an activation energy for this process was estimated to be 133 kJ mol(-1). The techniques of Si-29 MAS NMR and FTIR were both found to be unsuitable for quantifying dimorphic phase mixtures due to the ambiguity of the results they produced. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：303 / 319

页数：17