The role of the metal and the solvent in simple heterogeneous electron transfer reactions

被引：26

作者：

Fawcett, WR

机构：

来源：

ELECTROCHIMICA ACTA | 1997年 / 42卷 / 05期

关键词：

electrode kinetics; double layer effects; solvent effects;

D O I：

10.1016/S0013-4686(96)00331-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Solvent effects in simple electron transfer reactions are reviewed. It is shown that estimation of the outer sphere Gibbs activation energy is often difficult. Data for the electroreduction of Fe(H2O)(6)(3+) at single crystal gold electrodes are also discussed. This system shows a very large double layer effect. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：833 / 839

页数：7

共 37 条

[31] INFLUENCE OF SOLVENT DYNAMICS ON THE HETEROGENEOUS KINETICS OF A REACTION WITH A LARGE INNER-SHELL BARRIER - CHLORO(TETRAPHENYLPORPHINATO)MANGANESE(III) REDUCTION [J].