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Bispidine ligand effects on iron/hydrogen peroxide chemistry

被引：75
作者：
Bukowski, MR
Comba, P
Limberg, C
Merz, M
Que, L
Wistuba, T
机构：
[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
[3] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA
[4] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 10期
关键词：
coordination modes; iron; ligands; stereochemistry;
D O I：
10.1002/anie.200352523
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
...and yet so different. Non-heme iron complexes catalyze the stereoselective oxidation of C-H and C=C bonds. Isomeric FeIII- η1-hydroperoxo and FeIII-η2-peroxo complexes (see picture), important intermediates in these reactions, were studied by EPR, resonance Raman, and UV/Vis spectroscopies.
引用
收藏
页码：1283 / 1287
页数：5
相关论文
共 25 条
[1]   Radical chemistry of tert-butyl hydroperoxide (TBHP).: Part 1.: Studies of the FeIII-TBHP mechanism [J].
Barton, DHR ;
Le Gloahec, VN ;
Patin, H ;
Launay, F .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (06) :559-563
[2]   Iron coordination chemistry with tetra-, penta- and hexadentate bispidine-type ligands [J].
Börzel, H ;
Comba, P ;
Hagen, KS ;
Lampeka, YD ;
Lienke, A ;
Linti, G ;
Merz, M ;
Pritzkow, H ;
Tsymbal, LV .
INORGANICA CHIMICA ACTA, 2002, 337 :407-419
[3]  
Burger RM, 2000, STRUCT BOND, V97, P287
[4]   Spin state tuning of non-heme iron-catalyzed hydrocarbon oxidations:: participation of FeIII-OOH and FeV=O intermediates [J].
Chen, K ;
Costas, M ;
Que, L .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (05) :672-679
[5]   Bond-stretch isomerism: Trapped isomeric structures of hexacoordinate copper(II) bispidine chromophores along a Jahn-Teller active vibrational coordinate [J].
Comba, P ;
Hauser, A ;
Kerscher, M ;
Pritzkow, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (37) :4536-4540
[6]  
Comba P, 2002, CHEM-EUR J, V8, P5750, DOI 10.1002/1521-3765(20021216)8:24<5750::AID-CHEM5750>3.0.CO
[7]  
2-P
[8]   Bispidine copper(II) compounds: Effects of the rigid ligand backbone [J].
Comba, P ;
Lienke, A .
INORGANIC CHEMISTRY, 2001, 40 (20) :5206-5209
[9]  
COMBA P, UNPUB INORG CHEM
[10]  
Comba P., 2003, ANGEW CHEM, V115, P4675
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