学术探索
学术期刊
新闻热点
数据分析
智能评审

A selected ion flow tube study of the reactions of H3O+, NO+ and O2•+ with some oxygenated biogenic volatile organic compounds

被引：27
作者：
Amelynck, C
Schoon, N
Kuppens, T
Bultinck, P
Arijs, E
机构：
[1] Inst Aeron Spatiale Belgique, B-1180 Brussels, Belgium
[2] Univ Ghent, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium
来源：
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2005年 / 247卷 / 1-3期
关键词：
SIFT; oxygenated biogenic volatile organic compounds; ion/molecule reactions; rate constants;
D O I：
10.1016/j.ijms.2005.08.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The rate constants and product ion distributions of the reactions of H3O+, NO+ and O-2(center dot+) with 2-methyl-3-buten-2-ol, cis-3-hexen-1-ol, cis-3-hexenyl acetate, 1,8-cineole, 6-methyl-5-hepten-2-one, camphor and linalool have been determined at 150Pa and 297K using a selected ion flow tube (SIFT). All reactions were found to proceed at a rate close to the collision rate, calculated with the Su and Chesnavich model, using the polarizability and electric dipole moment of the compounds derived from B3LYP/aug-cc-pVDZ quantum chemical calculations. Additionally the product ion distributions of the reactions of these three ions with the terpenoid alcohols nerol and geraniol have been obtained. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：1 / 9
页数：9
相关论文
共 48 条
[1]   THE EMISSION OF (Z)-3-HEXEN-1-OL, (Z)-3-HEXENYLACETATE AND OTHER OXYGENATED HYDROCARBONS FROM AGRICULTURAL PLANT-SPECIES [J].
AREY, J ;
WINER, AM ;
ATKINSON, R ;
ASCHMANN, SM ;
LONG, WD ;
MORRISON, CL .
ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS, 1991, 25 (5-6) :1063-1075
[2]   Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review [J].
Atkinson, R ;
Arey, J .
ATMOSPHERIC ENVIRONMENT, 2003, 37 :S197-S219
[3]  
BACK J, 2005, GEOPHYS RES ABSTR, V7
[4]   Negative ion mass spectrometry and the detection of carbonyls and HCN front clover [J].
Custer, TG ;
Kato, S ;
Fall, R ;
Bierbaum, VM .
GEOPHYSICAL RESEARCH LETTERS, 2000, 27 (23) :3849-3852
[5]   Negative-ion CIMS: analysis of volatile leaf wound compounds including HCN [J].
Custer, TG ;
Kato, S ;
Fall, R ;
Bierbaum, VM .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2003, 223 (1-3) :427-446
[6]   Proton-transfer chemical-ionization mass spectrometry allows real-time analysis of volatile organic compounds released from cutting and drying of crops [J].
De Gouw, JA ;
Howard, CJ ;
Custer, TG ;
Baker, BM ;
Fall, R .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (12) :2640-2648
[7]   Emissions of volatile organic compounds from cut grass and clover are enhanced during the drying process [J].
de Gouw, JA ;
Howard, CJ ;
Custer, TG ;
Fall, R .
GEOPHYSICAL RESEARCH LETTERS, 1999, 26 (07) :811-814
[8]   A selected ion flow tube (SIFT), study of the reactions of H3O+, NO+ and O2+ ions with a series of alkenes;: in support of SIFT-MS [J].
Diskin, AM ;
Wang, TS ;
Smith, D ;
Spanel, P .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2002, 218 (01) :87-101
[9]  
FRISCH MJ, 2004, GAUSSIAN 03 REV B05
[10]   Ozonolysis at vegetation surfaces: A source of acetone, 4-oxopentanal, 6-methyl-5-hepten-2-one, and geranyl acetone in the troposphere [J].
Fruekilde, P ;
Hjorth, J ;
Jensen, NR ;
Kotzias, D ;
Larsen, B .
ATMOSPHERIC ENVIRONMENT, 1998, 32 (11) :1893-1902
12345