Influence of D/A Ratio on Photovoltaic Performance of a Highly Efficient Polymer Solar Cell System

被引:231
作者
Guo, Xia [1 ,2 ]
Zhang, Maojie [1 ]
Tan, Jiahui [3 ]
Zhang, Shaoqing [1 ]
Huo, Lijun [1 ]
Hu, Wenping [3 ]
Li, Yongfang [3 ]
Hou, Jianhui [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[3] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
conjugated polymers; polymer solar cells; balanced electron and hole mobility; FIELD-EFFECT TRANSISTORS; OPEN-CIRCUIT VOLTAGE; ELECTRON; COPOLYMER; AMBIPOLAR; METHANOFULLERENE; GENERATION; DEPENDENCE; MORPHOLOGY; TRANSPORT;
D O I
10.1002/adma.201202719
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new copolymer PIDTDTQx based on indacenodithiophene and quinoxaline is synthesized and characterized. The correlation between the D/A ratio, mobility, and photovoltaic properties, as well as morphology of the D/A blend based on a PIDTDTQx:PC70BM system is investigated. The power conversion efficiency of the polymer solar cells based on PIDTDTQx/PC70BM (1:4, w/w) reaches 7.51%.
引用
收藏
页码:6536 / 6541
页数:6
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