A convenient method for in situ generation of I2 using CuSO4/NaI and its applications to the deprotection of acetals, etherifications and iodolactonizations

被引：25

作者：

Bailey, AD ^{[1
]}

Cherney, SM ^{[1
]}

Anzalone, PW ^{[1
]}

Anderson, ED ^{[1
]}

Ernat, JJ ^{[1
]}

Mohan, RS ^{[1
]}

机构：

[1] Illinois Wesleyan Univ, Dept Chem, Bloomington, IL 61701 USA

来源：

SYNLETT | 2006年 / 02期

关键词：

acetals; chemoselectivity; ethers; lactones; iodine;

D O I：

10.1055/s-2005-923586

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient method for the in situ generation of I-2 using CuSO4/NaI has been developed. The applications of this method to the deprotection of acetals, etherifications and iodolactonizations have been demonstrated. The use of toxic and corrosive molecular iodine is avoided.

引用

页码：215 / 218

页数：4

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