Living/controlled radical polymerization of styrene mediated by nitroso compound: Kinetic and ESR studies

被引：26

作者：

Catala, JM ^{[1
]}

Jousset, S ^{[1
]}

Lamps, JP ^{[1
]}

机构：

[1] Univ Strasbourg 1, CNRS, Inst Charles Sadron, F-67083 Strasbourg, France

来源：

MACROMOLECULES | 2001年 / 34卷 / 25期

关键词：

D O I：

10.1021/ma010777s

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical polymerization of styrene in the presence of the nitroso-tert-octane have been studied at 90 and 110 degreesC. From kinetic and ESR experiments it has been established that the process presents the criteria of a living/controlled radical polymerization up to 50% monomer conversion. This has been explained by the initial formation of a nitroxide by addition of a styryl radical on the nitroso compound.

引用

页码：8654 / 8656

页数：3

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