Synthesis and crystal structure of the two-dimensional coordination polymer (Ph(3)Sn)(3)Fe(CN)(6)center dot H2O center dot 2CH(3)CN

被引：36

作者：

Lu, J ^{[1
]}

Harrison, WTA ^{[1
]}

Jacobson, AJ ^{[1
]}

机构：

[1] UNIV HOUSTON,DEPT CHEM,HOUSTON,TX 77204

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 14期

关键词：

D O I：

10.1021/ic960077h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An aqueous solution of K3Fe(CN)(6) reacts with an acetonitrile solution of Ph(3)SnCl to form the red layered polymeric compound (Ph(3)Sn)(3)Fe(CN)(6) . H2O . 2CH(3)CN. The structure of the compound contains one semilinear chain and one zigzag chain. The zigzag sheets formed by those two chains are connected by hydrogen bonds. Channels formed by the chains are filled with phenyl rings on tin atoms and the acetonitrile solvent molecules.

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页码：4271 / &

页数：4

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