Chlorobis[2-(diphenylphosphino)-phenolato-O,P]oxorhenium(V)

被引：9

作者：

Loiseau, F ^{[1
]}

Lucchese, Y ^{[1
]}

Dartiguenave, M ^{[1
]}

BelangerGariepy, F ^{[1
]}

Beauchamp, AL ^{[1
]}

机构：

[1] UNIV MONTREAL,DEPT CHIM,MONTREAL,PQ H3C 3J7,CANADA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196004106

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [ReClO(C18H14OP)(2)], contains severely distorted octahedra with a cis,cis,cis configuration. One of the phenolate O atoms is trans to the Re=O bond, whereas the two P atoms occupy cis sites. Departure from octahedral geometry can be interpreted in terms of the steric hindrance between the phosphine groups, the small bite of the P-O chelating agent and the tendency of the Re=O bond to repel The adjacent bonds. Bond lengths are Re=O 1.686 (4), Re-Cl 2.394(2), Re-P 2.443(2) and 2.451 (2), and Re-O(phenolate) 2.003 (4) (trans to Re=O) and 1.987 (4) Angstrom (trans to P).

引用

页码：1968 / 1971

页数：4

共 12 条

[1]

AHMED FR, 1973, J APPL CRYSTALLOGR, V6, P309

[2]

DARTIGUENAVE M, 1996, UNPUB

[3]

Enraf-Nonius, 1989, CAD 4 SOFTW VERS 5 0

[4] ON ENANTIOMORPH-POLARITY ESTIMATION [J].