Alkyne and Alkene Insertion into Metal-Heteroatom and Metal-Hydrogen Bonds: The Key Stages of Hydrofunctionalization Process

被引：115

作者：

Ananikov, Valentine P. ^{[1
]}

Beletskaya, Irina P. ^{[2
]}

机构：

[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

HYDROFUNCTIONALIZATION | 2013年 / 43卷

关键词：

Alkenes; Alkynes; Catalysis Insertion Mechanism; Selectivity; CARBON-CARBON; C-C; N BOND; PALLADIUM; VINYL; PD; ACTIVATION; COMPLEXES; HYDROTHIOLATION; REACTIVITY;

D O I：

10.1007/3418_2012_54

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this chapter we review mechanistic concepts of carbon-heteroatom bond formation involving hydrofunctionalization of double and triple carbon carbon bonds via migratory insertion pathway. A variety of useful synthetic procedures were developed within the scope of hydrofunctionalization reaction involving transition metal catalysts to change the direction of the addition reaction and to improve the selectivity of the process. Outstanding potential of multiple bonds activation and insertion in the metal complexes is far from being fully explored. The key factors determining insertion pathways into metal-heteroatom vs. metal hydrogen bonds and the influence on regioselectivity of the insertion remain to be revealed in nearest future.

引用

页码：1 / 19

页数：19

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