Methyltrioxorhenium-catalyzed oxidation of secondary and primary amines with hydrogen peroxide

被引：69

作者：

Yamazaki, S

机构：

[1] Toyama Industrial Technology Center, Takaoka, Toyama 933

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1997年 / 70卷 / 04期

关键词：

D O I：

10.1246/bcsj.70.877

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The methyltrioxorhenium-catalyzed oxidation of secondary amines and primary amines with hydrogen peroxide has been carried out. The oxidation of secondary amines afforded nitrones in good-to-excellent yield. Benzylamines were selectively oxidized to oximes, while general primary alkylamines possessing the alpha-C-H bond gave mixtures of oximes, nitroso dimers, and azoxy compounds.

引用

页码：877 / 883

页数：7

共 56 条

[21] OXIDATION OF CHLORIDE-IONS BY HYDROGEN-PEROXIDE, CATALYZED BY METHYLRHENIUM TRIOXIDE
HANSEN, PJ
ESPENSON, JH
[J]. INORGANIC CHEMISTRY, 1995, 34 (23) : 5839 - 5844
[22] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .122. METHYLTRIOXORHENIUM(VII) AS CATALYST FOR EPOXIDATIONS - STRUCTURE OF THE ACTIVE SPECIES AND MECHANISM OF CATALYSIS
HERRMANN, WA
FISCHER, RW
SCHERER, W
RAUCH, MU
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (08): : 1157 - 1160
[23] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .133. METHYLTRIOXORHENIUM AS A CATALYST OF THE BAEYER-VILLIGER OXIDATION
HERRMANN, WA
FISCHER, RW
CORREIA, JDG
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1994, 94 (02): : 213 - 223
[24] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .125. ALKYLRHENIUM OXIDES AS HOMOGENEOUS EPOXIDATION CATALYSTS - ACTIVITY, SELECTIVITY, STABILITY, DEACTIVATION
HERRMANN, WA
FISCHER, RW
RAUCH, MU
SCHERER, W
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1994, 86 (1-3): : 243 - 266
[25] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .100. METHYLTRIOXORHENIUM AS CATALYST FOR OLEFIN OXIDATION
HERRMANN, WA
FISCHER, RW
MARZ, DW
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (12): : 1638 - 1641
[26] SIMPLE AND EFFICIENT SYNTHESIS OF METHYLTRIOXORHENIUM (VII) - A GENERAL-METHOD
HERRMANN, WA
KUHN, FE
FISCHER, RW
THIEL, WR
ROMAO, CC
[J]. INORGANIC CHEMISTRY, 1992, 31 (21) : 4431 - 4432
[27] HUDLICKY M, 1990, OXIDATIONS ORGANIC C, P234
[28] METHYLTRIOXORHENIUM-CATALYZED OXIDATION OF A (THIOLATO)COBALT(III) COMPLEX BY HYDROGEN-PEROXIDE
HUSTON, P
ESPENSON, JH
BAKAC, A
[J]. INORGANIC CHEMISTRY, 1993, 32 (21) : 4517 - 4523
[29] JOSEPH R, 1995, SYNLETT, P1177
[30] KATALYTISCHE OXYDATION VON PRIMAREN AMINEN ZU OXIMEN MIT WASSERSTOFFPEROXYD
KAHR, K
BERTHER, C
[J]. CHEMISCHE BERICHTE-RECUEIL, 1960, 93 (01): : 132 - 136

← 1 2 3 4 5 6 →