Luminescent polynuclear d10 metal complexes

被引:1185
作者
Yam, VWW [1 ]
Lo, KKW [1 ]
机构
[1] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China
关键词
D O I
10.1039/a804249g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A number of polynuclear d(10) transition metal complexes have been found to exhibit interesting luminescence properties. The photoluminescence properties of polynuclear d(10) metal complexes are highly diversified. In the presence of a wide range of bridging and ancillary ligands, the excited states of such complexes have been suggested to range from metal-to-ligand charge-transfer, ligand-to-metal charge-transfer, metal-centred to ligand-centred in nature. Recent work on the photophysical and photochemical properties, as well as the applications of this class of luminescent polynuclear d(10) metal complexes will be described in this review article.
引用
收藏
页码:323 / 334
页数:12
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[11]   LUMINESCENCE FROM THE CHAIR AND CUBE ISOMERS OF AG4I4(PPH3)4 [J].
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