CuH-catalyzed reactions

被引：562

作者：

Deutsch, Carl ^{[1
]}

Krause, Norbert ^{[1
]}

Lipshutz, Bruce H. ^{[2
]}

机构：

[1] Univ Dortmund, D-44227 Dortmund, Germany

[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

CHEMICAL REVIEWS | 2008年 / 108卷 / 08期

关键词：

D O I：

10.1021/cr0684321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stryker's reagent or phosphine-stabilized hexamer is the most commonly used copper hydride species. This crystalline red solid have characteristics such as mildness of the reaction conditions, functional group compatibility, and excellent overall efficiencies. With the availability of several sources of copper hydride, the focus of current CuH chemistry continues to be on catalytic asymmetric processes. Also included in the report are reductions and related reactions like reduction of enones, enoates and related Michael acceptors mediated or catalyzed by copper hydride.

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页码：2916 / 2927

页数：12

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