Structural aspects of layered double hydroxides

被引：986

作者：

Evans, DG ^{[1
]}

Slade, RCT

机构：

[1] Beijing Univ Chem Technol, Minist Educ Key Lab Sci & Technol Controllable Ch, Beijing 100029, Peoples R China

[2] Univ Surrey, Dept Chem, Guildford GU2 7XH, Surrey, England

来源：

LAYERED DOUBLE HYDROXIDES | 2006年 / 119卷

关键词：

layered double hydroxide; hydrotalcite; structure; diffraction; polytype; order-disorder;

D O I：

10.1007/430_005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Layered double hydroxides (LDHs) have been known for a considerable time and have been widely studied. The basic features of their structure, involving positively charged brucite-like layers together with charge-balancing anions and water in interlayer galleries are well understood, but some detailed aspects of their structure have been the subject of controversy in the literature. In this article we review the wide range of experimental and theoretical studies of the structure of LDHs, highlighting areas of consensus and currently unresolved issues. We focus on the range of composition for which LDHs may be formed, possible layer stacking polytypes, arrangement of guest species in the interlayer galleries and the extent of order-disorder phenomena, both long-range and short-range, in the layers and interlayer galleries.

引用

页码：1 / 87

页数：87

共 335 条

[11]

Arakcheeva AV, 1996, KRISTALLOGRAFIYA+, V41, P1024

[12] Synthesis and characterization of polyoxovanadate-pillared Zn-Al layered double hydroxides: An x-ray absorption and diffraction study [J].

Barriga, C ;

Jones, W ;

Malet, P ;

Rives, V ;

Ulibarri, MA .

INORGANIC CHEMISTRY, 1998, 37 (08) :1812-1820

[13] Preparation and characterisation of a stable Rh catalyst for the partial oxidation of methane [J].

Basile, F ;

Fornasari, G ;

Gazzano, M ;

Kiennemann, A ;

Vaccari, A .

JOURNAL OF CATALYSIS, 2003, 217 (02) :245-252

[14] Composites of perylene chromophores and layered double hydroxides: Direct synthesis, characterization; and photo- and chemical stability [J].

Bauer, J ;

Behrens, P ;

Speckbacher, M ;

Langhals, H .

ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (03) :241-248

[15] Intercalation of noble metal complexes in LDH compounds [J].

Beaudot, P ;

De Roy, ME ;

Besse, JP .

JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (08) :2691-2698

[16] Preparation and characterization of intercalation compounds of layered double hydroxides with metallic oxalato complexes [J].

Beaudot, P ;

De Roy, ME ;

Besse, JP .

CHEMISTRY OF MATERIALS, 2004, 16 (05) :935-945

[17] Intercalation of platinum complex in LDH compounds [J].

Beaudot, P ;

De Roy, ME ;

Besse, JP .

JOURNAL OF SOLID STATE CHEMISTRY, 2001, 161 (02) :332-340

[18] A reexamination of hydrotalcite crystal chemistry [J].

Bellotto, M ;

Rebours, B ;

Clause, O ;

Lynch, J ;

Bazin, D ;

Elkaim, E .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (20) :8527-8534

[19] Synthesis and structure of the gibbsite intercalation compounds [LiAl2(OH)(6)]X {X=Cl, Br, NO3} and [LiAl2(OH)(6)]Cl center dot H2O using synchrotron X-ray and neutron powder diffraction [J].

Besserguenev, AV ;

Fogg, AM ;

Francis, RJ ;

Price, SJ ;

OHare, D ;

Isupov, VP ;

Tolochko, BP .

CHEMISTRY OF MATERIALS, 1997, 9 (01) :241-247

[20] A novel approach to micro-sample X-ray powder diffraction using nylon loops [J].

Bhuvanesh, NSP ;

Reibenspies, JH .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :1480-1481

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