Fabrication of superhydrophobic surface from a supramolecular organosilane with quadruple hydrogen bonding

被引：215

作者：

Han, JT

Lee, DH

Ryu, CY

Cho, KW ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, Dept Chem Engn, Pohang 790784, South Korea

[2] Rensselaer Polytech Inst, Dept Chem, Troy, NY 12180 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 15期

关键词：

D O I：

10.1021/ja0499400

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A supramolecular organosilane, 2-(3-(triethoxysilyl)propylaminocarbonylamino)-6-methyl-4[1H]pyrimidinone comprising quadruple hydrogen bonds has been synthesized in one step from commercially available starting materials. The synthesized supramolecular organosilane can be stabilized and phase-separated by dimerization via the linear array of quadruple hydrogen bonds in solution. This property of the supramolecular organosilane has been exploited to fabricate structuring materials having a superhydrophobic surface property. We have successfully generated the interconnected granular structure with adequate roughness for superhydrophobicity via sol-gel process. Copyright © 2004 American Chemical Society.

引用

页码：4796 / 4797

页数：2

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