Micelle-Templated Mesoporous Films of Magnesium Carbonate and Magnesium Oxide

被引：48

作者：

Eckhardt, B. ^{[1
]}

Ortel, E. ^{[1
]}

Polte, J. ^{[1
]}

Bernsmeier, D. ^{[1
]}

Goerke, O. ^{[2
]}

Strasser, P. ^{[1
]}

Kraehnert, R. ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

[2] Tech Univ Berlin, Inst Werkstoffwissensch, D-10587 Berlin, Germany

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 23期

关键词：

EISA; magnesium oxide; mesoporous material; micelle; self-assembly; PORE DIAMETER; OXIDATION; CATALYST; MGO; TRANSITION; CO;

D O I：

10.1002/adma.201104984

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Ordered mesoporous MgO films are synthesized via micelle-templating for the first time. The problems of low melting points, insolubility and excessive crystallization of the metal oxide precursors are overcome by synthesizing in-situ a magnesium nitrate-citric acid complex. The stepwise thermal transformation into magnesium carbonate and then MgO was studied as well as the evolution of the mesopore structure. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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收藏

页码：3115 / 3119

页数：5

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