Boron nitride nanotubes: Pronounced resistance to oxidation

被引:816
作者
Chen, Y [1 ]
Zou, J
Campbell, SJ
Le Caer, G
机构
[1] Australian Natl Univ, Res Sch Phys Sci & Engn, Dept Elect Mat Engn, Canberra, ACT 0200, Australia
[2] Univ Sydney, Electron Microscopy Unit, Sydney, NSW 2006, Australia
[3] Univ New S Wales, Australian Def Force Acad, Sch Phys Environm & Math Sci, Canberra, ACT 2600, Australia
[4] Univ Rennes 1, GMCM UMR CNRS 6626, F-35042 Rennes, France
关键词
D O I
10.1063/1.1667278
中图分类号
O59 [应用物理学];
学科分类号
摘要
Boron nitride (BN) nanotubes have the same nanostructure as carbon nanotubes but are found to exhibit significant resistance to oxidation at high temperatures. Our systematic study has revealed that BN,nanotubes are stable at 700degreesC in air and that some,thin nanotubes (diameter less than 20 nm) with perfect multiwalled cylindrical structure can survive up to 900degreesC. Thermogravimetric analysis reveals an onset temperature for oxidation of BN nanotubes of 800degreesC compared with only 400degreesC for carbon nanotubes under the same. conditions. This more pronounced resistance of BN nanotubes to oxidation is inherited from the hexagonal BN and also depends on the nanocrystalline structure. This high level of resistance to oxidation allows promising BN nanotube applications at high temperatures. (C) 2004 American Institute of Physics.
引用
收藏
页码:2430 / 2432
页数:3
相关论文
共 16 条
[1]   OPENING CARBON NANOTUBES WITH OXYGEN AND IMPLICATIONS FOR FILLING [J].
AJAYAN, PM ;
EBBESEN, TW ;
ICHIHASHI, T ;
IIJIMA, S ;
TANIGAKI, K ;
HIURA, H .
NATURE, 1993, 362 (6420) :522-525
[2]   Synthesis of boron nitride nanotubes at low temperatures using reactive ball milling [J].
Chen, Y ;
Fitz Gerald, JD ;
Williams, JS ;
Bulcock, S .
CHEMICAL PHYSICS LETTERS, 1999, 299 (3-4) :260-264
[3]   A solid-state process for formation of boron nitride nanotubes [J].
Chen, Y ;
Chadderton, LT ;
FitzGerald, J ;
Williams, JS .
APPLIED PHYSICS LETTERS, 1999, 74 (20) :2960-2962
[4]   Large-quantity production of high-yield boron nitride nanotubes [J].
Chen, Y ;
Conway, M ;
Williams, JS ;
Zou, J .
JOURNAL OF MATERIALS RESEARCH, 2002, 17 (08) :1896-1899
[5]  
Chen Y., UNPUB
[6]  
CHOPRA NG, 1998, SOLID STATE COMMUN, V105, P490
[7]   OXIDATIVE AND HYDROLYTIC STABILITY OF BORON-NITRIDE - A NEW APPROACH TO IMPROVING THE OXIDATION RESISTANCE OF CARBONACEOUS STRUCTURES [J].
COFER, CG ;
ECONOMY, J .
CARBON, 1995, 33 (04) :389-395
[8]   Nanotube growth during annealing of mechanically milled Boron [J].
Fitz Gerald, JD ;
Chen, Y ;
Conway, MJ .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2003, 76 (01) :107-110
[9]   Nanotubes in boron nitride laser heated at high pressure [J].
Golberg, D ;
Bando, Y ;
Eremets, M ;
Takemura, K ;
Kurashima, K ;
Yusa, H .
APPLIED PHYSICS LETTERS, 1996, 69 (14) :2045-2047
[10]   Transformation of BxCyNz nanotubes to pure BN nanotubes [J].
Han, WQ ;
Mickelson, W ;
Cumings, J ;
Zettl, A .
APPLIED PHYSICS LETTERS, 2002, 81 (06) :1110-1112