Transformation of BxCyNz nanotubes to pure BN nanotubes

被引:173
作者
Han, WQ
Mickelson, W
Cumings, J
Zettl, A [1 ]
机构
[1] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA
[2] Lawrence Berkeley Natl Lab, Div Sci Mat, Berkeley, CA 94720 USA
关键词
D O I
10.1063/1.1498494
中图分类号
O59 [应用物理学];
学科分类号
摘要
We demonstrate that multiwalled BxCyNz nanotubes can be efficiently converted to BN multiwalled nanotubes via an oxidation treatment. The microstructure and composition of the precursors and final products have been characterized by high-resolution transmission electron microscopy, electron energy-loss spectroscopy, and energy dispersive x-ray spectroscopy. The conversion process is monitored by thermogravimetric analysis. Carbon layers of BxCyNz nanotubes start to oxidize at 550 degreesC, thereby transforming BxCyNz nanotubes into pure BN nanotubes. The remarkable thermal stability of pure BN nanotubes in an oxidizing environment is also established. (C) 2002 American Institute of Physics.
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页码:1110 / 1112
页数:3
相关论文
共 11 条
[1]   Structural and electronic properties of composite BxCyNz nanotubes and heterojunctions [J].
Blase, X ;
Charlier, JC ;
De Vita, A ;
Car, R .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1999, 68 (03) :293-300
[2]   BORON-NITRIDE NANOTUBES [J].
CHOPRA, NG ;
LUYKEN, RJ ;
CHERREY, K ;
CRESPI, VH ;
COHEN, ML ;
LOUIE, SG ;
ZETTL, A .
SCIENCE, 1995, 269 (5226) :966-967
[3]   PURIFICATION OF NANOTUBES [J].
EBBESEN, TW ;
AJAYAN, PM ;
HIURA, H ;
TANIGAKI, K .
NATURE, 1994, 367 (6463) :519-519
[4]   MoO3-promoted synthesis of multi-walled BN nanotubes from C nanotube templates [J].
Golberg, D ;
Bando, Y ;
Kurashima, K ;
Sato, T .
CHEMICAL PHYSICS LETTERS, 2000, 323 (1-2) :185-191
[5]  
Han WQ, 2000, APPL PHYS A-MATER, V71, P83
[6]   Synthesis of aligned BxCyNz nanotubes by a substitution-reaction route [J].
Han, WQ ;
Cumings, J ;
Huang, XS ;
Bradley, K ;
Zettl, A .
CHEMICAL PHYSICS LETTERS, 2001, 346 (5-6) :368-372
[7]   Formation of boron nitride (BN) fullerene-like nanoparticles and (BN)xCy nanotubes using carbon nanotubes as templates [J].
Han, WQ ;
Bando, Y ;
Kurashima, K ;
Sato, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1999, 38 (7A) :L755-L757
[8]   Synthesis of boron nitride nanotubes from carbon nanotubes by a substitution reaction [J].
Han, WQ ;
Bando, Y ;
Kurashima, K ;
Sato, T .
APPLIED PHYSICS LETTERS, 1998, 73 (21) :3085-3087
[9]   Synthesis of nanoparticles and nanotubes with well-separated layers of boron nitride and carbon [J].
Suenaga, K ;
Colliex, C ;
Demoncy, N ;
Loiseau, A ;
Pascard, H ;
Willaime, F .
SCIENCE, 1997, 278 (5338) :653-655
[10]   THINNING AND OPENING OF CARBON NANOTUBES BY OXIDATION USING CARBON-DIOXIDE [J].
TSANG, SC ;
HARRIS, PJF ;
GREEN, MLH .
NATURE, 1993, 362 (6420) :520-522