Asymmetric transition states of allylation reaction: an ab initio molecular orbital study

被引：19

作者：

Gung, BW ^{[1
]}

Xue, XW ^{[1
]}

机构：

[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 21期

关键词：

D O I：

10.1016/S0957-4166(01)00533-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An ab initio MO study of the allylation of alpha-methoxypropanal by allylboronic acid has been carried out. The calculated most stable transition state arrangement was found to be similar to that proposed by Cornforth. The Felkin-Anh orientation was found to be less stable than the Cornforth-like arrangement at the B3LYP/6-31G* level of theory in the six-membered cyclic transition state. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2955 / 2959

页数：5

共 30 条

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