Nanoindentation of regenerated cellulose fibres

被引:41
作者
Gindl, W
Konnerth, J
Schöberl, T
机构
[1] BOKU Vienna, Dept Mat Sci & Proc Engn, A-1190 Vienna, Austria
[2] WOOD K PLUS, Competence Ctr Wood Composites & Wood Chem, A-4021 Linz, Austria
[3] Austrian Acad Sci, Erich Schmid Inst Mat Sci, A-8700 Leoben, Austria
关键词
elastic modulus; hardness; lyocell; nanoindentation; regenerated cellulose fibre; viscose;
D O I
10.1007/s10570-005-9017-0
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Nanoindentation was performed on cross sections of regenerated cellulose fibres with different structure and properties. Same as in single-fibre tensile tests, the elastic modulus of lyocell was higher than the elastic modulus of viscose. However, in spite of its tensile strength being twice as high as viscose, the hardness of lyocell was 15% lower than viscose. The overall degree of orientation of cellulose chains being higher in lyocell than in viscose, it is proposed that reduced lateral bonding in lyocell is the reason for the low hardness measured by nanoindentation compared to viscose.
引用
收藏
页码:1 / 7
页数:7
相关论文
共 13 条
[1]   Structure formation of regenerated cellulose materials from NMMO-solutions [J].
Fink, HP ;
Weigel, P ;
Purz, HJ ;
Ganster, J .
PROGRESS IN POLYMER SCIENCE, 2001, 26 (09) :1473-1524
[2]  
Fink HP, 2004, TECHN TEXT, V47, P126
[3]   Cell-wall hardness and Young's modulus of melamine-modified spruce wood by nano-indentation [J].
Gindl, W ;
Gupta, HS .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2002, 33 (08) :1141-1145
[4]   Mechanical properties of spruce wood cell walls by nanoindentation [J].
Gindl, W ;
Gupta, HS ;
Schöberl, T ;
Lichtenegger, HC ;
Fratzl, P .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2004, 79 (08) :2069-2073
[5]   Cellulose: Fascinating biopolymer and sustainable raw material [J].
Klemm, D ;
Heublein, B ;
Fink, HP ;
Bohn, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (22) :3358-3393
[6]  
LENZ J, 1988, PAPIER, V42, P683
[7]  
Mortimer SA, 1996, J APPL POLYM SCI, V60, P305, DOI 10.1002/(SICI)1097-4628(19960418)60:3<305::AID-APP3>3.3.CO
[8]  
2-9
[9]   Skin/core micro-structure in viscose rayon fibres analysed by X-ray microbeam and electron diffraction mapping [J].
Müller, M ;
Riekel, C ;
Vuong, R ;
Chanzy, H .
POLYMER, 2000, 41 (07) :2627-2632
[10]   AN IMPROVED TECHNIQUE FOR DETERMINING HARDNESS AND ELASTIC-MODULUS USING LOAD AND DISPLACEMENT SENSING INDENTATION EXPERIMENTS [J].
OLIVER, WC ;
PHARR, GM .
JOURNAL OF MATERIALS RESEARCH, 1992, 7 (06) :1564-1583