Dye sensitized solar cells (DSSCs) based on modified iron phthalocyanine nanostructured TiO2 electrode and PEDOT:PSS counter electrode

An iron phthalocyanine with tetra-sulphonated substituents (FeTsPc) was used as photosentizer for the development of dye sensitized nanostructured TiO2 solar cells. The influence ofsurface modification (TiO2 film treated with HCl and HNO3) and thermal annealing of TiO2 photo-electrode on the performance of dye sensitized solar cell (DSSC) having structure FTO/TiO2-FeTsPc/electrolyte/PEDOT: PSS (carbon added)/FTO was investigated through the analysis of current-voltage characteristics under illumination and electrochemical impedance spectra (EIS). The improvement in crystallinity of TiO2, decrease in the internal surface area and adsorbed amount of dye and increase in the lifetime of injected electrons upon thermal annealing of TiO2 photo-electrode affects the photovoltaic properties of DSSC. The increase in power conversion efficiency of DSSC based on nitric acid treatment for the photo-electrode is mainly attributed to the increase in photocurrent. A comparative photovoltaic investigation of DSSCs using HCl-treated TiO2 photo-electrode, indicates that the HNO3-treated photo-electrode retards back electron transfer at the interface with electrolyte and increases the amount of dye. (C) 2009 Elsevier B.V. All rights reserved.