Determination of parameters of electron transport in dye-sensitized solar cells using electrochemical impedance spectroscopy

被引:975
作者
Adachi, Motonari [1 ]
Sakamoto, Masaru
Jiu, Jinting
Ogata, Yukio
Isoda, Seiji
机构
[1] Kyoto Univ, Int Innovat Ctr, Isoda Lab, Inst Chem Res, Kyoto 6110011, Japan
[2] Kyoto Univ, Inst Adv Energy, Kyoto 6110011, Japan
关键词
NANOCRYSTALLINE TIO2; BACK-REACTION; RECOMBINATION; PERFORMANCE; DIFFUSION; CIRCUIT;
D O I
10.1021/jp061693u
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The same equation was derived from two different impedance models based on the quite different physical descriptions proposed by Kern et al.(1) and by Bisquert.(2,3) Reliable values of the parameters relating to electron transport in dye-sensitized solar cells can be determined from measured spectra by electrochemical impedance spectroscopy when careful analysis of the measured spectra is done based on the classification and clarification of the same impedance equation consequent from the two models. The requisites for making highly efficient dye-sensitized solar cells were proposed.
引用
收藏
页码:13872 / 13880
页数:9
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