Assembly and exchange of resorcinarene capsules monitored by fluorescence resonance energy transfer

被引:100
作者
Barrett, Elizabeth S.
Dale, Trevor J.
Rebek, Julius, Jr.
机构
[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA
[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
关键词
ENCAPSULATION;
D O I
10.1021/ja0700956
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Resorcinarenes were functionalized with fluorophores and fluorescence resonance energy transfer (FRET) was employed as a tool to probe the dynamic behavior of hydrogen-bonded hexameric assemblies at nanomolar concentrations. The encapsulation of a fluorescent guest inside the capsule made it possible to observe FRET across the mechanical boundary of the hexameric assembly.
引用
收藏
页码:3818 / +
页数:3
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