Novel fullerene-functionalised poly(terthiophenes)

被引：10

作者：

Chen, J.

Tsekouras, G.

Officer, D. L.

Wagner, P.

Wang, C. Y.

Too, C. O.

Wallace, G. G.

机构：

[1] Univ Wollongong, Intelligent Polymer Res Inst, Wollongong, NSW 2522, Australia

[2] Univ Wollongong, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia

[3] Massey Univ, Nanomat Res Ctr, Palmerston North, New Zealand

[4] Massey Univ, MacDiarmid Inst Adv Mat & Nanotechnol, Palmerston North, New Zealand

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2007年 / 599卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

fullerene; synthesis; electrochemistry; terthiophene;

D O I：

10.1016/j.jelechem.2006.09.007

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel fullerene-functionalised terthiophene monomer, N-methyl-2-(2-[2,2';5',2''-terthiophen-3'-yl]ethenyl)fullero [3,4]pyrrolidine (TTh-BB), has been successfully electropolymerised to form the homopolymer, P(TTh-BB). The polymer has been characterised using cyclic voltammetry (CV), UV-Vis spectroscopy, scanning electron microscopy (SEM) and Raman spectroscopy. Preliminary studies into the use of this novel polymer as a cathode material in a lithium battery have been carried out here. (c) 2006 Elsevier B.V. All rights reserved.

引用

收藏

页码：79 / 84

页数：6

相关论文

共 27 条

[1] ORGANIC MOLECULAR SOFT FERROMAGNETISM IN A FULLERENE-C60 [J].

ALLEMAND, PM ;

KHEMANI, KC ;

KOCH, A ;

WUDL, F ;

HOLCZER, K ;

DONOVAN, S ;

GRUNER, G ;

THOMPSON, JD .

SCIENCE, 1991, 253 (5017) :301-303

[2] Polymerization of C60 fullerene thin films by UV pulsed laser irradiation [J].

Alvarez-Zauco, E ;

Sobral, H ;

Basiuk, EV ;

Saniger-Blesa, JM ;

Villagrán-Muniz, M .

APPLIED SURFACE SCIENCE, 2005, 248 (1-4) :243-247

[3] The first ''charm bracelet'' conjugated polymer: An electroconducting polythiophene with covalently bound fullerene moieties [J].

Benincori, T ;

Brenna, E ;

Sannicolo, F ;

Trimarco, L ;

Zotti, G ;

Sozzani, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (06) :648-651

[4] Novel battery using conducting polymers: Polyindole and polyaniline as active materials [J].

Cai, ZJ ;

Geng, MM ;

Tang, ZY .

JOURNAL OF MATERIALS SCIENCE, 2004, 39 (12) :4001-4003

[5] ELECTROCHEMISTRY OF FULLERENE FILMS [J].

CHLISTUNOFF, J ;

CLIFFEL, D ;

BARD, AJ .

THIN SOLID FILMS, 1995, 257 (02) :166-184

[6] The design and synthesis of porphyrin/oligiothiophene hybrid monomers [J].

Collis, GE ;

Campbell, WM ;

Officer, DL ;

Burrell, AK .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (11) :2075-2084

[7] Grafting of buckminsterfullerene onto polythiophene: novel intramolecular donor-acceptor polymers [J].

Ferraris, JP ;

Yassar, A ;

Loveday, DC ;

Hmyene, M .

OPTICAL MATERIALS, 1998, 9 (1-4) :34-42

[8] Carbon materials for the electrochemical storage of energy in capacitors [J].

Frackowiak, E ;

Béguin, F .

CARBON, 2001, 39 (06) :937-950

[9] Electrochemical storage of lithium multiwalled carbon nanotubes [J].

Frackowiak, E ;

Gautier, S ;

Gaucher, H ;

Bonnamy, S ;

Beguin, F .

CARBON, 1999, 37 (01) :61-69

[10] An all-polymer charge storage device [J].

Gofer, Y ;

Sarker, H ;

Killian, JG ;

Poehler, TO ;

Searson, PC .

APPLIED PHYSICS LETTERS, 1997, 71 (11) :1582-1584