Synthesis and characterization of nano-sized gold-palladium bimetallic particles dispersed in polymer thin film matrix

被引：52

作者：

Deki, S ^{[1
]}

Akamatsu, K ^{[1
]}

Hatakenaka, Y ^{[1
]}

Mizuhata, M ^{[1
]}

Kajinami, A ^{[1
]}

机构：

[1] Kobe Univ, Fac Engn, Dept Sci & Chem Engn, Nada Ku, Kobe, Hyogo 6578501, Japan

来源：

NANOSTRUCTURED MATERIALS | 1999年 / 11卷 / 01期

关键词：

D O I：

10.1016/S0965-9773(99)00019-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have prepared nano-sized Au/Pd bimetallic particles with various compositions dispersed in nylon 11 thin films by thermal relaxation technique. The films obtained were characterized by TEM, EDX, XPS and visible absorption spectroscopy. The Au/Pd molar ratio in the bimetallic particles could be varied over the entire composition range by controlling the initial deposition amount of constituent metals. It was found that the mean size of the dispersed particles decreased from 5.3 to 3.2 nm in diameter with increasing the Pd content in the bimetallic particles. Optical absorption due to surface plasmon resonance absorption of the Au particles decreased with decreasing the Au/Pd ratio, which can be caused by the changes in the band structure of the Au particles due to alloying with Pd. (C) 1999 Acta Metallurgica Inc.

引用

页码：59 / 65

页数：7

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