Self-Buffering Hybrid Gold-Polyoxometalate Catalysts for the Catalytic Cyclization of Acid-Sensitive Substrates

被引：34

作者：

Dupre, Nathalie ^{[1
]}

Brazel, Christian ^{[1
]}

Fensterbank, Louis ^{[1
]}

Malacria, Max ^{[1
]}

Thorimbert, Serge ^{[1
]}

Hasenknopf, Bernold ^{[1
]}

Lacote, Emmanuel ^{[1
,2
]}

机构：

[1] UPMC Sorbonne Univ, Inst Parisien Chim Mol UMR CNRS 7201, F-75005 Paris, France

[2] ICSN CNRS, F-91198 Gif Sur Yvette, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 41期

关键词：

allenes; gold; organic-inorganic hybrid composites; polyoxometalates; protonation; HIGHLY EFFICIENT; INTERCLUSTER COMPOUND; COMPLEXES; OXIDATION; CYCLOISOMERIZATION; EPOXIDATION; ACTIVATION; STABILITY; LIGANDS; ALLENES;

D O I：

10.1002/chem.201201007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Grafting of a gold complex to an organo-polyoxometalate delivers catalytically active bitopic hybrids. The gold end activates allenes, while the metal-oxide surface can capture protons (see scheme). The scope of the gold-catalyzed oxacyclization of allenols is expanded to highly sensitive tertiary benzylic alcohols. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12962 / 12965

页数：4

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