Synthesis of Fe nanoparticles@graphene composites for environmental applications

被引：214

作者：

Guo, Juan ^{[1
]}

Wang, Ruiyu ^{[1
]}

Tjiu, Weng Weei ^{[2
]}

Pan, Jisheng ^{[2
]}

Liu, Tianxi ^{[1
]}

机构：

[1] Fudan Univ, State Key Lab Mol Engn Polymers, Dept Macromol Sci, Shanghai 200433, Peoples R China

[2] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore

来源：

JOURNAL OF HAZARDOUS MATERIALS | 2012年 / 225卷

基金：

中国国家自然科学基金;

关键词：

Fe nanoparticle; Graphene; Dye removal; Magnetic property; ZERO-VALENT IRON; CARBON NANOTUBES; AQUEOUS-SOLUTION; REMOVAL; WATER; OXIDE; CORE; GROUNDWATER; REDUCTION; DECHLORINATION;

D O I：

10.1016/j.jhazmat.2012.04.065

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Fe nanoparticles@graphene composites (FGC) are successfully synthesized by using graphene oxide (GO) as a supporting matrix. GO is first treated with Fe3+ to form Fe3+@GO complexes. Then, by adding NaBH4 solution, Fe3+ and GO are simultaneously reduced in situ to Fe and graphene respectively, forming FGC hybrid composites. The structures, properties and applications of the hybrids thus obtained are investigated by X-ray diffraction, Raman spectroscopy, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, thermogravimetric analysis and magnetization measurements. The hybrids are also evaluated for decolorization of methyl blue solution, a model dye in wastewater of dyeing industry. Compared with bare Fe particles, the high removal capacities of FGC are due to the increased adsorption sites in the hybrids, which are achieved by inhibiting the particle aggregation and reducing the size of Fe nanoparticles. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：63 / 73

页数：11

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