Proton transport of water in acid-base reactions of 7-hydroxyquinoline

被引：46

作者：

Park, Sun-Young ^{[1
]}

Lee, Young-Shin ^{[1
]}

Kwon, Oh-Hoon ^{[1
]}

Jang, Du-Jeon ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem, Seoul 151742, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 08期

关键词：

LIQUID WATER; HYDROGEN; MECHANISM; DYNAMICS; STATE; IONS; SPECTROSCOPY; COMPLEXES; BRIDGES; TRIPLE;

D O I：

10.1039/b817698a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sequential, Grotthuss-type, proton-transport mechanism of water has been experimentally observed in the excited- state tautomerization of a 7-hydroxyquinoline molecule complexed cyclically with two water molecules in diethyl ether.

引用

页码：926 / 928

页数：3

共 32 条

[1] THE GROTTHUSS MECHANISM [J].

AGMON, N .

CHEMICAL PHYSICS LETTERS, 1995, 244 (5-6) :456-462

[2] Water-chain clusters:: Vibronic spectra of 7-hydroxyquinoline•(H2O)2 [J].

Bach, A ;

Coussan, S ;

Müller, A ;

Leutwyler, S .

JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (03) :1192-1203

[3] A theory of water and ionic solution, with particular reference to hydrogen and hydroxyl ions [J].

Bernal, JD ;

Fowler, RH .

JOURNAL OF CHEMICAL PHYSICS, 1933, 1 (08) :515-548

[4] Volumes and hydration warmth of ions [J].

Born, M .

ZEITSCHRIFT FUR PHYSIK, 1920, 1 :45-48

[5]

De Grotthuss C, 1806, Ann. Chim, V58, P54

[6] PROTON TRANSFER ACID-BASE CATALYSIS + ENZYMATIC HYDROLYSIS .I. ELEMENTARY PROCESSES [J].

EIGEN, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1964, 3 (01) :1-&

[7] Theoretical characterization of the structures and reactivity of 7-hydroxyquinoline-(H2O)n (n=1-3) complexes [J].

Fang, WH .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (28) :5567-5573

[8] Autoionization in liquid water [J].

Geissler, PL ;

Dellago, C ;

Chandler, D ;

Hutter, J ;

Parrinello, M .

SCIENCE, 2001, 291 (5511) :2121-2124

[9] Vibrational gating of double hydrogen tunneling in porphycene [J].

Gil, Michal ;

Waluk, Jacek .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (05) :1335-1341

[10] Proton-coupled electron transfer in soybean lipoxygenase [J].

Hatcher, E ;

Soudackov, AV ;

Hammes-Schiffer, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (18) :5763-5775

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