Well-defined fullerene-containing homopolymers and diblock copolymers with high fullerene content and their use for solution-phase and bulk organization

被引：56

作者：

Ball, ZT

Sivula, K

Fréchet, JMJ

机构：

[1] Univ Calif Berkeley, Div Mat Sci, Lawrence Berkeley Lab, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Dept Chem & Chem Engn, Berkeley, CA 94720 USA

来源：

MACROMOLECULES | 2006年 / 39卷 / 01期

关键词：

D O I：

10.1021/ma052325b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A fullerene-containing norbomene derivative is used for ring-opening metathesis polymerization to synthesize living polymers with high fullerene content. Incorporation of fullerene at every repeat of a small monomer allows high fullerene content and short inter-fullerene distances in a soluble polymer. The living nature of the polymerization also allows the synthesis of diblock copolymers, which exhibit micellar aggregation in solution and phase separation with interpenetrating C-60-domains in a thin film upon TEM imaging.

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页码：70 / 72

页数：3

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