Polymer Mechanochemistry: Force Enabled Transformations

被引:53
作者
Wiggins, Kelly M. [1 ]
Brantley, Johnathan N. [1 ]
Bielawski, Christopher W. [1 ]
机构
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
关键词
ULTRASONIC DEGRADATION; MECHANICAL ACTIVATION; CATALYSTS; OPPORTUNITIES; RESOLUTIONS; COPOLYMERS; ENZYMES; MODEL; STATE;
D O I
10.1021/mz300167y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this viewpoint, we highlight the ability of mechanical force to overcome the limitations associated with using thermal or photochemical stimuli to facilitate chemical transformations. Emphasis will be directed toward examples of new chemical reactions that are accessed through externally applied mechanical forces, as these are illustrative of the emerging concept of using polymer chemistry to drive the synthesis of small molecules. In parallel, we offer perspectives on the potential applications of polymer mechanochemistry in the development of novel synthetic strategies.
引用
收藏
页码:623 / 626
页数:4
相关论文
共 64 条
[11]   Reaction dynamics in the formidable gap [J].
Boulatov, Roman .
PURE AND APPLIED CHEMISTRY, 2011, 83 (01) :25-41
[12]   RETRACTED: Unclicking the Click: Mechanically Facilitated 1,3-Dipolar Cycloreversions (Retracted Article) [J].
Brantley, Johnathan N. ;
Wiggins, Kelly M. ;
Bielawski, Christopher W. .
SCIENCE, 2011, 333 (6049) :1606-1609
[13]   Dynamic resolutions in asymmetric synthesis [J].
Caddick, S ;
Jenkins, K .
CHEMICAL SOCIETY REVIEWS, 1996, 25 (06) :447-&
[14]   The thermal decomposition of sodium ethyl [J].
Carothers, WH ;
Coffman, DD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1929, 51 (1-4) :588-593
[15]   Mechanically-Induced Chemical Changes in Polymeric Materials [J].
Caruso, Mary M. ;
Davis, Douglas A. ;
Shen, Qilong ;
Odom, Susan A. ;
Sottos, Nancy R. ;
White, Scott R. ;
Moore, Jeffrey S. .
CHEMICAL REVIEWS, 2009, 109 (11) :5755-5798
[16]   Dynamic combinatorial chemistry [J].
Corbett, Peter T. ;
Leclaire, Julien ;
Vial, Laurent ;
West, Kevin R. ;
Wietor, Jean-Luc ;
Sanders, Jeremy K. M. ;
Otto, Sijbren .
CHEMICAL REVIEWS, 2006, 106 (09) :3652-3711
[17]   Force-induced activation of covalent bonds in mechanoresponsive polymeric materials [J].
Davis, Douglas A. ;
Hamilton, Andrew ;
Yang, Jinglei ;
Cremar, Lee D. ;
Van Gough, Dara ;
Potisek, Stephanie L. ;
Ong, Mitchell T. ;
Braun, Paul V. ;
Martinez, Todd J. ;
White, Scott R. ;
Moore, Jeffrey S. ;
Sottos, Nancy R. .
NATURE, 2009, 459 (7243) :68-72
[18]   GENERAL MODEL FOR PREDICTION OF MOLECULAR-WEIGHT DISTRIBUTIONS OF DEGRADED POLYMERS - DEVELOPMENT AND COMPARISON WITH ULTRASONIC DEGRADATION EXPERIMENTS [J].
GLYNN, PAR ;
VANDERHO.BM ;
REILLY, PM .
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1972, A 6 (08) :1653-1664
[19]   DEGRADATION OF POLYSTYRENE IN SOLUTION BY ULTRASONATION - MOLECULAR-WEIGHT DISTRIBUTION STUDY [J].
GLYNN, PAR ;
VANDERHO.BM .
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1973, A 7 (08) :1695-1719
[20]   RETRO-DIELS-ALDER REACTIONS .3. KINETICS OF THERMAL DECOMPOSITIONS OF EXO- AND ENDO-DICYCLOPENTADIENE [J].
HERNDON, WC ;
GRAYSON, CR ;
MANION, JM .
JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (03) :526-&