(4,4)-Connected Self-penetrating Pillared-Layered Metal-Organic Framework Based on a Nanosized Flexible Aromatic Carboxylic Acid Ligand

被引：37

作者：

Cao, Li-Hui ^{[1
]}

Li, Hai-Yang ^{[1
]}

Zang, Shuang-Quan ^{[1
]}

Hou, Hong-Wei ^{[1
]}

Mak, Thomas C. W. ^{[1
,2
,3
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China

[2] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[3] Chinese Univ Hong Kong, Ctr Novel Funct Mol, Shatin, Hong Kong, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2012年 / 12卷 / 09期

基金：

中国国家自然科学基金;

关键词：

COORDINATION POLYMERS; RETICULAR CHEMISTRY; MOLECULAR TECTONICS; CRYSTAL-STRUCTURES; NETWORK; CONSTRUCTION; DESIGN; POLYROTAXANE; TOPOLOGY; NETS;

D O I：

10.1021/cg3007712

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel coordination polymer based on a nanosized flexible aromatic carboxylic acid ligand has been successfully synthesized by solvothermal reaction, [Cd(obda)(0.5)(bpy)(H2O)]center dot 2H(2)O (1) (H(4)obda = 1,4-bis(4-oxy-1,2-benzenedicarboxylic acid)benzene, bpy = 4,4'- bipyridine), exhibiting a (4,4)-connected self-penetrating pillared-layered metal-organic framework. In addition, photoluminescence was also performed on 1.

引用

页码：4299 / 4301

页数：3

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