Silyl-substituted cyclopropyl carbenoids

被引:19
作者
Creary, X
Jiang, ZQ
Butchko, M
McLean, K
机构
[1] Dept. of Chemistry and Biochemistry, University of Notre Dame, Notre Dame
关键词
D O I
10.1016/0040-4039(95)02266-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Cyclopropyl carbeniods, generated from dibromocyclopropanes and methyllithium, insert preferentially into SiMe(3) activated C-H bonds. In other cases, allene formation remains the dominant process.
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页码:579 / 582
页数:4
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