The reaction of ferrocene with mercuric chloride revisited:: 'Cp2Fe*2HgCl2' = [(C5H5)Fe(C5H4HgCl)]2[Hg2Cl6], comparison of its molecular structure with that of chloromercuriferrocene

被引：11

作者：

Sünkel, K ^{[1
]}

Kiessling, T ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 637卷

关键词：

ferrocene; ferricenium; mercury; crystal structures;

D O I：

10.1016/S0022-328X(01)00969-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 'blue adduct' formed from the decomposition of the red 'Cp2Fe*7HgCl(2)' and formulated as 'Cp2Fe*2HgCl(2)' was characterized by X-ray crystallography as the ring-mercurated ferricenium. salt [(C5H5)Fe(C5H4HgCl)](2)[Hg2Cl6]. For comparison, the neutral [(C5H5)Fe(C5H4HgCl)] was also studied by single-crystal diffractometry. Both compounds have the HgCl group within the plane of the cyclopentadienyl ring with no Fe-Hg interaction. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：796 / 799

页数：4

共 17 条

[1]

BURSHTEIN LF, 1997, RUSS J COORD CHEM, V23, P856

[2] Transmetallation reactions of planar chiral cyclopalladated ferrocenylimines with metallic mercury [J].