Changes to polymer morphology caused by uv irradiation .1. Surface damage

被引:34
作者
Kaczmarek, H
机构
[1] Faculty of Chemistry, Nicolaus Copernicus University, 87-100 Toruń
关键词
morphology; degradation; uv irradiation;
D O I
10.1016/0032-3861(96)81086-X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The influence of u.v. irradiation on the surface morphology of some commercial polymers was investigated using scanning electron microscopy (SEM). The photodegraded samples exhibited a high degree of surface damage. The formation of cracks and holes resulting from the degradation and evolution of volatile products was observed. In polymers undergoing photocrosslinking, the agglomeration of particles was clearly seen. Polymer photodegradation in the presence of hydrogen peroxide as an acceleration agent revealed its etching action.
引用
收藏
页码:189 / 194
页数:6
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