Visible-Light-Induced Aerobic Oxidation of Alcohols in a Coupled Photocatalytic System of Dye-Sensitized TiO2 and TEMPO

被引：442

作者：

Zhang, Miao ^{[1
]}

Chen, Chuncheng ^{[1
]}

Ma, Wanhong ^{[1
]}

Zhao, Jincai ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 50期

关键词：

photooxidation; radical reactions; TEMPO; TiO2; visible light;

D O I：

10.1002/anie.200803630

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Like a differential gear: Upon irradiation with visible light, excited dye molecules inject electrons into TiO2 and form dye radicals, which can oxidize TEMPO to TEMPO+, which in turn oxidizes alcohols in the presence of O2 selectively to corresponding aldehydes. One reason for the selectivity is that the irradiation is downshifted to visible light. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9730 / 9733

页数：4

共 28 条

[1]

[Anonymous], 2007, ANGEW CHEM-GER EDIT

[2]

[Anonymous], 2007, ANGEW CHEM

[3] Efficient Mn-Cu and Mn-Co-TEMPO-catalysed oxidation of alcohols into aldehydes and ketones by oxygen under mild conditions [J].