High open circuit voltage organic photovoltaic cells fabricated using 9,9′-bifluorenylidene as a non-fullerene type electron acceptor

被引：56

作者：

Kim, Hee Un ^{[1
,2
]}

Kim, Ji-Hoon ^{[1
,2
]}

Suh, Hongsuk ^{[1
,2
]}

Kwak, Jeonghun ^{[3
]}

Kim, Dongwook ^{[4
]}

Grimsdale, Andrew C. ^{[5
]}

Yoon, Sung Cheol ^{[6
]}

Hwang, Do-Hoon ^{[1
,2
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

[2] Pusan Natl Univ, Chem Inst Funct Mat, Pusan 609735, South Korea

[3] Dong A Univ, Dept Elect Engn, Pusan 604714, South Korea

[4] Kyonggi Univ, Dept Chem, Suwonsi 443760, Gyeonggi, South Korea

[5] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[6] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 93期

基金：

新加坡国家研究基金会;

关键词：

SOLAR-CELLS; DERIVATIVES; POLYMERS;

D O I：

10.1039/c3cc46557h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have found that 9,9'BF can be used as an electron acceptor for P3HT-based OPVs while similar devices using 4,4'BP do not show any photovoltaic effect. This can be related to the respective aromaticity and antiaromaticity of the reduced forms of 9,9'BF or 4,4'BP. The OPV device fabricated using P3HT and 9,9'BF exhibited a PCE of 2.28% with a V-oc of 1.07 V, a J(sc) of 5.04 mA cm(-2), and a FF of 0.42.

引用

页码：10950 / 10952

页数：3

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