Synthesis and enantiomer separation of a modified tris(2,2′-bipyridine)ruthenium(II) complex

被引：33

作者：

Holder, E

Schoetz, G

Schurig, V

Lindner, E

机构：

[1] Univ Tubingen, Inst Inorgan Chem, D-72076 Tubingen, Germany

[2] Univ Tubingen, Inst Organ Chem, D-72076 Tubingen, Germany

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 16期

关键词：

D O I：

10.1016/S0957-4166(01)00407-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral [5-(4-hydroxybutyl)-5'-methyl-2.2'-bipyridine]-bis(2.2'-bipyridine)-ruthenium(II)-bis(hexafluoroantimonate) complex 3 was prepared and characterized by different NMR techniques and successfully separated into enantiomers by electrokinetic chromatography using anionic carboxymethyl-beta -cyclodextrin as chiral mobile phase additive (CMPA). The optimum separation conditions were obtained with 40 mM borate buffer at pH 9.5 and 7.5 mg/mL of the chiral selector at 20 degreesC. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2289 / 2293

页数：5