Thiyl radical induced isomerisations of maleate esters provide a convenient route to fumarates and furanones

被引：20

作者：

Harrowven, DC ^{[1
]}

Hannam, JC ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

TETRAHEDRON | 1999年 / 55卷 / 30期

关键词：

alkenes; cyclisation; isomerisations; lactones; radicals and radical reactions; sulfur chemistry;

D O I：

10.1016/S0040-4020(99)00496-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Maleate esters can be converted into fumarate esters in near quantitative yield through exposure to thiyl radicals generated in refluxing hexane by photolysis of diphenyl disulfide. When conditions are applied to dialkyl (hydroxyalkyl)maleate esters akin to 3, 2(5H)-furanones are given in good yield. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：9341 / 9346

页数：6

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