Double C-H activation in a Rh-NHC complex leading to the isolation of a 14-electron Rh(III) complex

被引：111

作者：

Dorta, R ^{[1
]}

Stevens, ED ^{[1
]}

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 16期

关键词：

D O I：

10.1021/ja049545+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvent-dependent interaction of ItBu with a Rh(I)-olefin complex leads to the isolation of two precursors en route to a unique double cyclometalation process. Abstraction of the chloride ligand from the resulting complex enables the isolation of a bare" 14-electron Rh(III) complex. Copyright © 2003 American Chemical Society."

引用

页码：5054 / 5055

页数：2

共 33 条

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