Synthesis and some reactions of the first chiral tin hydride containing a C-2-symmetric binaphthyl substituent

被引：94

作者：

Nanni, D

Curran, DP

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM ORGAN A MANGINI,I-40136 BOLOGNA,ITALY

[2] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 08期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0957-4166(96)00300-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Starting from pure (S)-2,2'-bis(bromomethyl)-1,1'-binaphthyl, the synthesis of a new chiral, enantiomerically pure dinaphthostannepin is described. Preliminary reactions of this hydride with a racemic organic halide under radical conditions gave the reduced product in up to 41% enantiomeric excess, depending on the experimental conditions. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2417 / 2422

页数：6

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