Electrochemical molecular recognition: pathways between complexation and signalling

被引：276

作者：

Beer, PD

Gale, PA

Chen, GZ

机构：

[1] Univ Oxford, Inorgan Chem Lab, Dept Chem, Oxford OX1 3QR, England

[2] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 12期

关键词：

D O I：

10.1039/a901462d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This perspective examines the mechanisms by which electrochemical recognition of various charged and neutral guest species by redox-active receptor molecules takes place. Particular emphasis is given to the intramolecular signalling pathway employed in each case. These include electrostatic interactions (through space or through conjugated bonds), conformational changes in the redox centre in complexation and guest interference to an already present communication pathway in the host.

引用

页码：1897 / 1909

页数：13

共 40 条

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