Microphase separation and wetting properties of palmitate-graft-poly(vinyl alcohol) films

被引：10

作者：

Biver, C ^{[1
]}

de Crevoisier, G ^{[1
]}

Girault, S ^{[1
]}

Mourran, A ^{[1
]}

Pirri, R ^{[1
]}

Razet, JC ^{[1
]}

Leibler, L ^{[1
]}

机构：

[1] ESPCI, CNRS, ATOFINA, UMR 167, F-75231 Paris 05, France

来源：

MACROMOLECULES | 2002年 / 35卷 / 07期

关键词：

D O I：

10.1021/ma010526j

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Bulk and surface organization properties of grafted copolymers having an hydrophilic poly(vinyl alcohol) backbone and hydrophobic palmitic side chains were investigated. A structural study shows the existence of a microphase separation into lamellar structures for grafting ratios of only 0.09. Water wettability of films obtained by solvent casting from these grafted copolymers indicates a good segregation and organization of the alkyl chains at the surface of the films even at grafting ratio as low as 0.04. The quality of the solvent used during the copolymer film formation is shown to have a strong influence on organization and wetting properties of these materials. The existence of specific interactions of H-bond type in the PVA phase seems to be responsible for a strong incompatibility between the hydrophilic backbone and the hydrophobic side chains leading to such surprisingly good bulk and surface organizations.

引用

页码：2552 / 2559

页数：8

共 41 条

[21] CRYSTALLOGRAPHIC STUDY ON MEMBRANES OBTAINED FROM ALKYLATED POLYVINYL ALCOHOLS [J].

MATHIS, A ;

LEMOIGNE, J ;

GRAMAIN, P .

EUROPEAN POLYMER JOURNAL, 1973, 9 (04) :283-292

[22]

MATSUMOTO T, 1971, KOBUNSHI KAGAKU, V28, P315

[23]

Matsumoto T., 1971, KOBUNSHI KAGAKU, V28, P610, DOI 10.1295/koron1944.28.610

[24]

MOURRAN A, 1999, PMSE P AM CHEM SOC, V80, P175

[25] Influence of blend composition on phase separation and dewetting of thin polymer blend films [J].

Müller-Buschbaum, P ;

Gutmann, JS ;

Stamm, M .

MACROMOLECULES, 2000, 33 (13) :4886-4895

[26]

NAKAHAMA S, 1995, POLYM PREPR, V36, P57

[27] Excitation of surface deformation modes of a phase-separating polymer blend on a patterned substrate [J].

Nisato, G ;

Ermi, BD ;

Douglas, JF ;

Karim, A .

MACROMOLECULES, 1999, 32 (07) :2356-2364

[28] STRUCTURE OF CRYSTALLINE POLYMERS WITH UNBRANCHED LONG SIDE CHAINS [J].

PLATE, NA ;

SHIBAEV, VP ;

PETRUKHIN, BS ;

ZUBOV, YA ;

KARGIN, VA .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1971, 9 (08) :2291-+

[29]

QIU YX, 1995, CHINESE J POLYM SCI, V13, P112

[30] ENVIRONMENTALLY INDUCED RESTRUCTURING OF POLYMER SURFACES AND ITS INFLUENCE ON THEIR WETTING CHARACTERISTICS IN AN AQUEOUS ENVIRONMENT [J].

RUCKENSTEIN, E ;

GOURISANKAR, SV .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1985, 107 (02) :488-502

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